Width of phonon sidebands in the Brownian oscillator model.

نویسندگان

  • Jun Ye
  • Yang Zhao
  • Nathaniel Ng
  • Jianshu Cao
چکیده

The line width dependence of zero-phonon lines and phonon sidebands on temperature, bath dissipation, and electron-phonon coupling is studied for an underdamped Brownian oscillator model with an Ohmic dissipative bath. Factors determining the line widths vary from the zero-phonon lines to the phonon sidebands. The control-parameter space of line broadening has been mapped out, revealing that the line widths of the zero-phonon lines and phonon sidebands are linearly dependent on both the temperature and the Huang-Rhys factor. It is also found that the dependence of the line widths on the bath damping factor is linear for the zero-phonon lines and quadratic for the phonon sidebands.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Optical and transport properties of single crystal rubrene: A theoretical study

Optical and charge transport properties of single crystal rubrene are investigated using the multi-mode Brownian oscillator (MBO) model, the charge hopping model with quantum nuclear tunneling, and the Munn–Silbey approach. The MBO model is adopted to calculate absorption and photoluminescence spectra, yielding results in excellent agreement with measurements. In addition, temperature dependenc...

متن کامل

Low-temperature zero phonon lineshapes with various Brownian oscillator spectral densities

The Brownian oscillator model has been successfully employed for modeling solvation dynamics in numerous femtosecond measurements. To a very large extent, this work has been interpreted on the basis of high-temperature limits of the theory. We present an analysis of the low temperature limit, which is particularly important for hole burning, photon echo, and single molecule spectroscopic experi...

متن کامل

Array-induced collective transport in the Brownian motion of coupled nonlinear oscillator systems

Brownian motion of an array of harmonically coupled particles subject to a periodic substrate potential and driven by an external bias is investigated. In the linear response limit (small bias), the coupling between particles may enhance the diffusion process, depending on the competition between the harmonic chain and the substrate potential. An analytical formula of the diffusion rate for the...

متن کامل

Stochastic excitation and delayed oscillation of a micro-oscillator

Stochastic processes in the form of the classical Brownian motion or internal phonon fluctuations may be studied by the use of a microcantilever. We present certain dynamic aspects of the behavior of the noise and the delayed fluctuations exhibited by a microcantilever. In particular, we present an analytic solution describing the transient response of the oscillator and discuss how self-excita...

متن کامل

Multimode vibronic spectra of the Holstein molecular crystal model.

Vibronic spectra of the Holstein model for molecular crystals are investigated using the dynamical mean field theory with the additional aid of the multi-mode Brownian oscillator model. The effects of temperature, intermolecular transfer integral, damping constant and quadratic coupling on the vibronic spectra are examined, and spectra in the presence of two phonon modes are studied in detail. ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • The journal of physical chemistry. B

دوره 113 17  شماره 

صفحات  -

تاریخ انتشار 2009